Linked Life Data

19836824

Source:http://linkedlifedata.com/resource/pubmed/id/19836824

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
10
pubmed:dateCreated
2009-11-12
pubmed:abstractText
The magnetic mixed hemimicelles solid-phase extraction (MMHSPE), based on the adsorption of cation surfactant octadecyltrimethylammonium bromide (OTMABr) onto magnetite nanoparticles (Fe(3)O(4) NPs) to form mixed hemimicelles, was proposed for the preconcentration of several sulfonamides (SAs) compounds including sulfamethoxazole (SMX), sulfamethoxydiazine (SMD), sulfadimethoxine (SDM) and sulfaquinoxaline (SQX) from environmental water samples. This method avoided the time-consuming column-passing process of loading large volume samples in traditional SPE through the rapid isolation of OTMABr-coated Fe(3)O(4) NPs with an adscititious magnet. Mixed hemimicelles formed on the surface of Fe(3)O(4) NPs by OTMABr showed great adsorptive tendency towards analytes. The OTMABr-coated Fe(3)O(4) NPs adsorbents were easy to be prepared, low cost and environmentally friendly. A comprehensive study on the adsorption conditions such as the amount of the surfactant, the solution pH, the desorption condition and the maximum extraction sample volume were optimized. A concentration factor of 1000 was achieved by the extraction of 500 mL of environmental water samples using MMHSPE. Detection limits obtained for SMX, SMD, SDM and SQX were 0.026, 0.024, 0.033 and 0.030 microg L(-1), respectively. Good recoveries (70-102%) with low relative standard deviations (1-6%) were achieved in analyzing spiked water samples. Low concentration of SQX was found in hospital primary and final sewage effluent sample.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1879-1298
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
77
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1306-12
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Analysis of sulfonamides in environmental water samples based on magnetic mixed hemimicelles solid-phase extraction coupled with HPLC-UV detection.
pubmed:affiliation
College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't