Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2009-3-2
pubmed:abstractText
A multifunctional electrodialytic generator (EDG) for capillary ion chromatography (CIC) is described. The same device can generate acidic, basic or saline eluents. Two oppositely charged ion exchange beads are used to fabricate the EDG; the dual ion exchanger configuration ensures the production of gas-free eluent, obviating the need of a gas removal device used with single ion exchanger EDG's. The ability of the same EDG to produce different eluents is governed solely by the choice of the respective feed solutions; this is presently demonstrated by generation of diverse eluents such as Na(2)CO(3)/NaHCO(3), CH(3)SO(3)H, and KNO(3). The EDG is implemented simply in a commercial cross fitting and has been tested up pressures to 2000psi. Under typical operating conditions, the zero current concentration (open circuit penetration, OCP) is negligible. The generated eluent concentration linearly increases with applied current with a slope that is essentially Faradaic. The device permits both isocratic and gradient operation with good reproducibility, as demonstrated by the analysis of anions using HCO(3)(-)/CO(3)(2-) EDG.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1873-3778
pubmed:author
pubmed:issnType
Electronic
pubmed:day
20
pubmed:volume
1216
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2412-6
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
A multifunctional dual membrane electrodialytic eluent generator for capillary ion chromatography.
pubmed:affiliation
School of Pharmacy, East China University of Science and Technology, Shanghai, China. bcyang06@hotmail.com
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't