Source:http://linkedlifedata.com/resource/pubmed/id/15018523
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
6
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pubmed:dateCreated |
2004-3-15
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pubmed:abstractText |
Gel-permeation chromatography (GPC) has been used to analyze transition-metal-based squares, triangles, and related supramolecular complexes. Using rhenium-containing molecular squares of different sizes, a linear calibration curve has been established, which was used for confirming the relative sizes of other assemblies. GPC can also discriminate cyclic trimers and tetramers of a dirhodium building block. Preparative GPC has been used to resolve macroscopic samples of a rhenium-based supramolecular mixture into pure syn and anti isomers. A mixture of "triangle" and "square" has also been successfully separated.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Mar
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pubmed:issn |
0020-1669
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
22
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pubmed:volume |
43
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2013-7
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pubmed:year |
2004
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pubmed:articleTitle |
Characterization and purification of supramolecular metal complexes using gel-permeation chromatography.
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pubmed:affiliation |
Department of Chemistry, Institute for Environmental Catalysis, and Center for Nanofabrication and Molecular Self-Assembly, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
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pubmed:publicationType |
Journal Article
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