Linked Life Data

9588011

Source:http://linkedlifedata.com/resource/pubmed/id/9588011

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
1998-6-4
pubmed:abstractText
The influence of mixed micellar systems on retention and selectivity in micellar electrokinetic chromatography is examined using linear solvation energy relationships (LSER). Systems that were investigated include mixed bile salts [sodium deoxycholate (SDC) and sodium cholate (SC)] and mixed sodium dodecyl sulfate (SDS)-bile salt systems (e.g., SDS-SC and SDS-SDC). The retention behavior in individual and mixed micellar systems is primarily determined by size and hydrogen bond acceptor strengths of solutes. Through a comparative study of the LSER coefficients in the individual and mixed micellar systems, it was concluded that hydrogen bonding interactions have a significant effect on selectivity of these pseudostationary phases in electrokinetic chromatography. The interactive properties of the mixed micelles are different from the constituent individual micelles, however, the overall characteristics are closer to one of the bile salt micelles in the mixture even at the equimolar compositions.
pubmed:grant
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
0021-9673
pubmed:author
pubmed:issnType
Print
pubmed:day
3
pubmed:volume
802
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
35-47
pubmed:dateRevised
2009-1-15
pubmed:meshHeading
pubmed:year
1998
pubmed:articleTitle
Characterization of mixed micellar pseudostationary phases in electrokinetic chromatography using linear solvation energy relationships.
pubmed:affiliation
North Carolina State University, Department of Chemistry, Raleigh 27695-8204, USA.
pubmed:publicationType
Journal Article, Comparative Study, Research Support, U.S. Gov't, P.H.S.