Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2010-1-13
pubmed:abstractText
The adsorption of hexahexylduodecithiophene (12T) on a Au(111) electrode was investigated by using cyclic voltammetry (CV) and in situ electrochemical scanning tunneling microscopy (EC-STM) in 0.10 M HClO(4). Potential control at 0.20 V (vs RHE) revealed adlayer structures of mostly folded and rarely angular (oblique) and extended conformations on a reconstructed Au(111)-(square root(3) x 22) surface. The angular and extended conformations predominate when the electrode potential is increased to 0.35 and 0.60 V. Folded structures are still evident, but dynamic STM studies showed unfolding of this conformation. With molecular STM imaging of 12T adlayers, we address the packing arrangement and conformational changes of 12T admolecules on the reconstructed Au(111) electrode surface.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jan
pubmed:issn
1520-5827
pubmed:author
pubmed:issnType
Electronic
pubmed:day
19
pubmed:volume
26
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
982-9
pubmed:year
2010
pubmed:articleTitle
Direct observation of conformational changes of beta-substituted duodecithiophene on a Au(111)-(square root(3) x 22) substrate using in situ electrochemical STM in 0.1 M HClO4.
pubmed:affiliation
Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, Aoba-yama 04, Sendai 980-8579, Japan. bvtongol@mnl.ust.edu.ph
pubmed:publicationType
Journal Article