Source:http://linkedlifedata.com/resource/pubmed/id/18549212
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
28
|
| pubmed:dateCreated |
2008-7-9
|
| pubmed:abstractText |
Spontaneous symmetry-breaking of a racemic mixture of supramolecular triginal prisms into chiral domains on a Au(111) surface is observed by scanning tunneling microscopy (STM). High-resolution STM analysis enables the structural aspects of each enantiomeric domain to be elucidated. The ability to resolve chirality on achiral surfaces has potential applications in heterogeneous stereoselective synthesis and catalysis.
|
| pubmed:grant | |
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
|
| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
1520-5126
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
16
|
| pubmed:volume |
130
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
8878-9
|
| pubmed:meshHeading |
pubmed-meshheading:18549212-Gold,
pubmed-meshheading:18549212-Macromolecular Substances,
pubmed-meshheading:18549212-Microscopy, Scanning Tunneling,
pubmed-meshheading:18549212-Models, Molecular,
pubmed-meshheading:18549212-Organometallic Compounds,
pubmed-meshheading:18549212-Pyridines,
pubmed-meshheading:18549212-Stereoisomerism,
pubmed-meshheading:18549212-Surface Properties
|
| pubmed:year |
2008
|
| pubmed:articleTitle |
Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface.
|
| pubmed:affiliation |
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing, China 100080.
|
| pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.,
Research Support, Non-U.S. Gov't,
Research Support, N.I.H., Extramural
|