Linked Life Data

17258392

Source:http://linkedlifedata.com/resource/pubmed/id/17258392

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1-2
pubmed:dateCreated
2007-7-30
pubmed:abstractText
A solid phase extraction procedure has been established for chromium speciation in natural water samples. The procedure is based on the solid phase extraction of the Cr(VI)-ammonium pyrrolidine dithiocarbamate (APDC) chelate on multiwalled carbon nanotubes (MWNTs). After oxidation of Cr(III) to Cr(VI) by using hydrogen peroxide, the presented method was applied to the determination of the total chromium. The level of Cr(III) is calculated by difference of total chromium and Cr(VI) levels. The procedure was optimized for some analytical parameters including pH, eluent type, flow rates of sample and eluent, matrix effects, etc. The detection limit based on 3 sigma criterion was 0.90 microg L(-1) for Cr(VI). The adsorption capacity of multiwalled carbon nanotubes was 9.50 mg g(-1) Cr (VI). The presented method was applied for the speciation of chromium in natural water sample with satisfactory results (recoveries>95%, R.S.D.'s<9%).
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
0304-3894
pubmed:author
pubmed:issnType
Print
pubmed:day
17
pubmed:volume
147
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
219-25
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
Multiwalled carbon nanotubes for speciation of chromium in environmental samples.
pubmed:affiliation
Gaziosmanpasa University, Faculty of Science and Arts, Chemistry Department, 60250 Tokat, Turkey.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't