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16671773
Source:
http://linkedlifedata.com/resource/pubmed/id/16671773
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rdf:type
pubmed:Citation
lifeskim:mentions
umls-concept:C0002074
,
umls-concept:C0030230
,
umls-concept:C0332514
,
umls-concept:C1100545
pubmed:issue
10
pubmed:dateCreated
2006-5-4
pubmed:abstractText
[reaction; see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center.
pubmed:grant
http://linkedlifedata.com/resource/pubmed/grant/GM33049
,
http://linkedlifedata.com/resource/pubmed/grant/R01 GM033049-31
pubmed:commentsCorrections
http://linkedlifedata.com/resource/pubmed/commentcorrection/16671773-11735524
,
http://linkedlifedata.com/resource/pubmed/commentcorrection/16671773-11784175
,
http://linkedlifedata.com/resource/pubmed/commentcorrection/16671773-12929397
,
http://linkedlifedata.com/resource/pubmed/commentcorrection/16671773-16018642
pubmed:language
eng
pubmed:journal
http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset
IM
pubmed:chemical
http://linkedlifedata.com/resource/pubmed/chemical/Alkaloids
,
http://linkedlifedata.com/resource/pubmed/chemical/Indoles
,
http://linkedlifedata.com/resource/pubmed/chemical/Palladium
,
http://linkedlifedata.com/resource/pubmed/chemical/Spiro Compounds
,
http://linkedlifedata.com/resource/pubmed/chemical/horsfiline
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1523-7060
pubmed:author
pubmed-author:BrennanMegan KMK
,
pubmed-author:TrostBarry MBM
pubmed:issnType
Print
pubmed:day
11
pubmed:volume
8
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2027-30
pubmed:dateRevised
2011-5-23
pubmed:meshHeading
pubmed-meshheading:16671773-Alkaloids
,
pubmed-meshheading:16671773-Alkylation
,
pubmed-meshheading:16671773-Catalysis
,
pubmed-meshheading:16671773-Indoles
,
pubmed-meshheading:16671773-Molecular Structure
,
pubmed-meshheading:16671773-Palladium
,
pubmed-meshheading:16671773-Spiro Compounds
,
pubmed-meshheading:16671773-Stereoisomerism
pubmed:year
2006
pubmed:articleTitle
Palladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline.
pubmed:affiliation
Department of Chemistry, Stanford University, California 94305, USA. bmtrost@stanford.edu
pubmed:publicationType
Journal Article
,
Research Support, U.S. Gov't, P.H.S.
,
Research Support, Non-U.S. Gov't
,
Research Support, N.I.H., Extramural