15496112

Source:http://linkedlifedata.com/resource/pubmed/id/15496112

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0002074, umls-concept:C0022634, umls-concept:C0332514, umls-concept:C0596514
pubmed:issue	22
pubmed:dateCreated	2004-10-21
pubmed:abstractText	[reaction: see text] The combination of catalytic palladium(0) and Trost ligand provides an effective catalyst for the rearrangement of allyl beta-ketoesters. The mechanism of the transformation involves formation of pi-allyl palladium intermediates which undergo enantioselective attack by ketone enolates. Decarboxylation of beta-ketocarboxylates allows regiospecific generation of enolates under extremely mild conditions.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Oct
pubmed:issn	1523-7060
pubmed:author	pubmed-author:BurgerErin CEC, pubmed-author:TungeJon AJA
pubmed:issnType	Print
pubmed:day	28
pubmed:volume	6
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4113-5
pubmed:year	2004
pubmed:articleTitle	Asymmetric allylic alkylation of ketone enolates: an asymmetric Claisen surrogate.
pubmed:affiliation	Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA.
pubmed:publicationType	Journal Article