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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
22
pubmed:dateCreated
2003-11-17
pubmed:abstractText
A method has been developed for the simultaneous determination of low molecular weight aliphatic amines and ammonia in the atmosphere. Analyte gases are collected quantitatively in high-purity deionized water of a planar diffusion scrubber, and the resultant solution is analyzed by ion chromatography. A 1-h cycle analysis could be continuously repeated. The calibrations for the amines are linear between 5 and 500 pptv. The detection limits are a few pptv with RSD of less than 3%. The calibration for ammonia shows severe curvature at high concentrations so that second-order fitting is required for accurate determination. This method was successfully applied to the environmental air analyses. The major amines in the atmosphere were trimethylamine, dimethylamine, and methylamine, and the temporal variations were closely correlated with that of ammonia, implying their identical emission sources.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Nov
pubmed:issn
0003-2700
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
75
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6141-6
pubmed:year
2003
pubmed:articleTitle
Development of an automated method for simultaneous determination of low molecular weight aliphatic amines and ammonia in ambient air by diffusion scrubber coupled to ion chromatography.
pubmed:affiliation
Department of Chemistry, Yonsei University, Seoul 120-749, Korea. ihchang@staff.uiuc.edu
pubmed:publicationType
Journal Article