The formation of peptidyl-dehydroalanine from either peptidyl-tyrosine by phenyl transfer, or from peptidyl-serine, which is coupled with the formation of 5-imidazolinone by the two neighboring residues, produces an 4-methylidene-imidazole-5-one active site of some amino acid ammonia-lyases; the 4-methylidene-imidazole-5-one, is formed autocatalytically by cyclization and dehydration of the sequence ASG.
| Predicate | Object |
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| rdf:type | |
| rdfs:comment |
The formation of peptidyl-dehydroalanine from either peptidyl-tyrosine by phenyl transfer, or from peptidyl-serine, which is coupled with the formation of 5-imidazolinone by the two neighboring residues, produces an 4-methylidene-imidazole-5-one active site of some amino acid ammonia-lyases; the 4-methylidene-imidazole-5-one, is formed autocatalytically by cyclization and dehydration of the sequence ASG.
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| rdfs:subClassOf | |
| rdfs:label |
peptidyl-dehydroalanine anabolism from peptidyl-tyrosine or peptidyl-serine,
peptidyl-dehydroalanine biosynthetic process from peptidyl-tyrosine or peptidyl-serine,
peptidyl-dehydroalanine formation from peptidyl-tyrosine or peptidyl-serine,
peptidyl-dehydroalanine synthesis from peptidyl-tyrosine or peptidyl-serine
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| skos:exactMatch |