Linked Life Data

9809786

Source:http://linkedlifedata.com/resource/pubmed/id/9809786

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2-3
pubmed:dateCreated
1999-1-19
pubmed:abstractText
1H double-quantum (DQ) solid-state NMR spectroscopy under fast magic-angle spinning (MAS) is introduced as a new spectroscopic tool for the investigation of the structure and local chain dynamics of elastomers. Dipolar connectivities between the protons of the various functional groups can be directly established from the highly resolved DQ solid-state NMR spectra as is shown for a series of cross-linked poly(styrene-co-butadiene). More quantitatively, residual dipolar couplings within and between the functional groups are evaluated selectively from the build-up curves of the double-quantum signals in the limit of the spin-pair approximation. In particular, the CH-CH and the CH2-CH couplings of butadiene, which both act predominantly along the chain-segment direction, have been measured relative to the CH2 coupling. The total build-up intensity is correlated with the cross-link density.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
0926-2040
pubmed:author
pubmed:issnType
Print
pubmed:volume
12
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
139-52
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
1998
pubmed:articleTitle
Selective residual dipolar couplings in cross-linked elastomers by 1H double-quantum NMR spectroscopy.
pubmed:affiliation
Max-Planck-Institut für Polymerforschung, Mainz, Germany.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't