Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
1995-5-9
pubmed:abstractText
The kinetic behaviour of dental composite is traditionally studied, considering only the isothermal behaviour, whereas a fast and highly non-isothermal bulk polymerization is expected as a consequence of the significant heat developed due to the exothermic nature of the polymerization reaction. In this paper the photopolymerization kinetics of a commercial dental composite activated by visible light are analysed by differential scanning calorimetry. This technique is applied to determine the degree of reaction and the glass transition temperature of thin layers of the composite matrix, at different isothermal cure temperatures. A phenomenological kinetic model is then integrated with an energy balance in order to analyse the cure behaviour of thicker composite layers. The full model results indicate that non-isothermal cure conditions may be achieved, obtaining higher values for the glass transition temperature and the degree of reaction.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Dec
pubmed:issn
0142-9612
pubmed:author
pubmed:issnType
Print
pubmed:volume
15
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1221-8
pubmed:dateRevised
2008-11-21
pubmed:meshHeading
pubmed:year
1994
pubmed:articleTitle
Photopolymerization of dental composite matrices.
pubmed:affiliation
Department of Materials Science, University of Lecce, Italy.
pubmed:publicationType
Journal Article