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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
5
|
pubmed:dateCreated |
1994-10-10
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pubmed:abstractText |
Porcine pancreatic (PPL), Candida cylindracea (CCL) and Pseudomonas cepacia (LPS) lipases, suspended in organic solvents, were used to regioselectively acylate methyl 6-O-butyryl-alpha-D- and L-allopyranosides and methyl 6-O-butyryl-3-deoxy-alpha-D- and L-ribo-hexopyranosides. Both the D- and the L-3-deoxy sugars showed a complete regioselectivity, while the reactions of the allosides proved to be less regioselective. This indicates that the presence of the hydroxyl group at C-3 is an unfavourable factor for the action of the lipases.
|
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
|
pubmed:chemical | |
pubmed:status |
MEDLINE
|
pubmed:month |
Nov
|
pubmed:issn |
0968-0896
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pubmed:author | |
pubmed:issnType |
Print
|
pubmed:volume |
1
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pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
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pubmed:pagination |
375-80
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:7521747-Acylation,
pubmed-meshheading:7521747-Animals,
pubmed-meshheading:7521747-Burkholderia cepacia,
pubmed-meshheading:7521747-Candida,
pubmed-meshheading:7521747-Glycosides,
pubmed-meshheading:7521747-Hydroxylation,
pubmed-meshheading:7521747-Lipase,
pubmed-meshheading:7521747-Magnetic Resonance Spectroscopy,
pubmed-meshheading:7521747-Molecular Structure,
pubmed-meshheading:7521747-Pancreas,
pubmed-meshheading:7521747-Substrate Specificity,
pubmed-meshheading:7521747-Swine
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pubmed:year |
1993
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pubmed:articleTitle |
Enzymic acylation of methyl D- and L-glycopyranosides: influence of the 3-hydroxyl group.
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pubmed:affiliation |
Dipartimento di Chimica e Biochimica Medica, Università di Milano, Italy.
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pubmed:publicationType |
Journal Article,
In Vitro,
Research Support, Non-U.S. Gov't
|