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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
23
pubmed:dateCreated
2011-7-20
pubmed:abstractText
LaCo(2)B(2) with a ThCr(2)Si(2)-type (so-called "122") structure composed of alternately stacked La and CoB layers exhibits metallic electrical conductivity and Pauli paramagnetic behavior down to 2 K. Bulk superconductivity with a T(c) of ?4??K emerges upon substituting with dopant elements, i.e., isovalent substitution to form (La(1-x)Y(x))Co(2)B(2), or aliovalent substitution to form La(Co(1-x)Fe(x))(2)B(2). According to the density functional theory calculations, highly covalent bonding between Co 3d dominating the Fermi level and B 2p levels deeper than the Fermi level removes magnetic ordering from Co 3d electrons even in the undoped samples. This is a first Co-based superconductor among the 122-type family.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
1079-7114
pubmed:author
pubmed:issnType
Electronic
pubmed:day
10
pubmed:volume
106
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
237001
pubmed:year
2011
pubmed:articleTitle
LaCo2B2: a Co-based layered superconductor with a ThCr2Si2-type structure.
pubmed:affiliation
Frontier Research Center, Tokyo Institute of Technology, Midori-ku, Yokohama, Japan.
pubmed:publicationType
Journal Article