Source:http://linkedlifedata.com/resource/pubmed/id/21588564
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 9
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| pubmed:dateCreated |
2011-5-18
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| pubmed:abstractText |
In the title mononuclear complex, [La(NO(3))(3)(C(22)H(26)N(2)O(4))]·CH(3)OH, the La(III) ion is coordinated by three bidentate nitrate counter-ions and one zwitterionic 6,6'-dimeth-oxy-2,2'-[(cyclo-hexane-1,2- di-yl)bis-(nitriliomethyl-idyne)]diphenolate ligand through two phenolate and two meth-oxy O atoms, while the protonated N atoms remain uncoordinated. H atoms located on the two N atoms are involved in intra-molecular hydrogen bonds with the deprotonated phenol O atoms, indicating that proton migration occurs during the lanthanum complexation.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:issn |
1600-5368
|
| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
66
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m1177
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2010
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| pubmed:articleTitle |
{6,6'-Dimeth-oxy-2,2'-[(cyclo-hexane-1,2-di-yl)bis-(nitriliomethyl-idyne)]diphenolato}trinitratolanthanum(III) methanol monosolvate.
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| pubmed:affiliation |
School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
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| pubmed:publicationType |
Journal Article
|