Source:http://linkedlifedata.com/resource/pubmed/id/21581158
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 12
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
The title compound, (C(4)H(12)N)(3)[CuMo(2)S(8)]·C(3)H(7)NO, was obtained from the self-assembly of tetra-thio-molybdate, tetra-methyl-ammonium nitrate and cuprous sulfide in dimethyl-formamide (DMF). The asymmetric unit contains three (NMe(4))(+) cations, one [Mo(2)S(8)Cu](3-) anion and one DMF solvent mol-ecule, and no obvious inter-actions are observed between these species. The trinuclear anion can be viewed as fused [MoS(4)Cu](-) units sharing a copper center. The geometric parameters of the trivalent anion are comparable to those reported for other related salts including isomorphous anions, namely (NEt(4))(2)(PPh(4))[Mo(2)S(8)Cu] (a) and (Ph(3)P=N=PPh(3))(2)(NEt(4))[W(2)S(8)Cu]·2CH(3)CN (b). However, the Mo-Cu-Mo angle is found to be 160.24?(3)° for the title salt, while this angle is 162.97?(2)° in (a) and the W-Cu-W angle is 170.3?(2)° in (b), indicating that the largest deviation from linearity is in the title compound.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
64
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m1546
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2008
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| pubmed:articleTitle |
Tris(tetra-methyl-ammonium) tetra-?(2)-sulfido-tetra-sulfidocopper(I)dimolyb-denum(VI) N,N-dimethyl-formamide solvate.
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| pubmed:publicationType |
Journal Article
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