Source:http://linkedlifedata.com/resource/pubmed/id/21541430
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
22
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| pubmed:dateCreated |
2011-5-30
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| pubmed:abstractText |
The synthesis, structural and magnetic characterisation of trinuclear manganese cluster, [Mn(3)O(O(2)C-anth)(6)(HOCH(3))(3)] 1 (where O(2)C-anth = 9-anthracenecarboxylate), with crystallographic three-fold (C(3)) symmetry, are described. The cluster was prepared by a carboxylate exchange reaction between HO(2)C-anth and [Mn(12)O(12)(O(2)CMe)(16)(H(2)O)(4)] with concomitant fragmentation of the dodecanuclear Mn core of the starting material to form a trinuclear Mn(3)(?(3)-O) cluster capped by six carboxylate ligands. Bond valence sum calculations and SQUID magnetometric measurements establish the oxidation states of the metal ions as Mn(II)·2 Mn(III) which are antiferromagnetically coupled.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jun
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| pubmed:issn |
1477-9234
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
14
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| pubmed:volume |
40
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
5891-4
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| pubmed:year |
2011
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| pubmed:articleTitle |
A mixed valence manganese triangle in a trigonal lattice: structure and magnetism.
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| pubmed:affiliation |
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
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| pubmed:publicationType |
Journal Article
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