Source:http://linkedlifedata.com/resource/pubmed/id/21508554
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
7
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pubmed:dateCreated |
2011-4-21
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pubmed:abstractText |
Batch tests were conducted to evaluate the influences of several common dissolved anions in groundwater on the reduction of para-chloronitrobenzene (p-CNB) by zero-valent iron (ZVI). The results showed that p-CNB reduction was enhanced by both Cl(-) and SO(4)(2-). HCO(3)(-) could either improve or inhibit p-CNB reduction, depending on whether the mixing speed was intense enough to rapidly eliminate Fe-carbonate complex deposited on ZVI surface. Above a concentration of 100?mg?L(-1), NO(3)(-) increased the p-CNB reduction rate. The reduction rate by ClO(4)(-) decreased because the ClO(4)(-) competed with p-CNB for electrons. The p-CNB reduction was inhibited by PO(4)(3-), SiO(3)(2-) and humic acid, in the order humic acid < PO(4)(3-) < SiO(3)(2-), since these ions could form inner-sphere complexes on iron surface. The reaction even ceased when the ion concentrations were greater than 4, 0.5, and 30?mg?L(-1), respectively. The results indicated that common dissolved anions in groundwater should be taken into account when ZVI is applied for contaminated groundwater remediation.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/4-chloronitrobenzene,
http://linkedlifedata.com/resource/pubmed/chemical/Anions,
http://linkedlifedata.com/resource/pubmed/chemical/Humic Substances,
http://linkedlifedata.com/resource/pubmed/chemical/Iron,
http://linkedlifedata.com/resource/pubmed/chemical/Nitrobenzenes
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pubmed:status |
MEDLINE
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pubmed:issn |
0273-1223
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
63
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1485-90
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pubmed:meshHeading |
pubmed-meshheading:21508554-Anions,
pubmed-meshheading:21508554-Humic Substances,
pubmed-meshheading:21508554-Iron,
pubmed-meshheading:21508554-Kinetics,
pubmed-meshheading:21508554-Nitrobenzenes,
pubmed-meshheading:21508554-Oxidation-Reduction,
pubmed-meshheading:21508554-Water Pollution, Chemical,
pubmed-meshheading:21508554-Water Purification,
pubmed-meshheading:21508554-Water Supply
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pubmed:year |
2011
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pubmed:articleTitle |
Effects of common dissolved anions on the reduction of para-chloronitrobenzene by zero-valent iron in groundwater.
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pubmed:affiliation |
School of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, China. le.c@mail.scut.edu.cn
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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