Source:http://linkedlifedata.com/resource/pubmed/id/21476538
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
10
|
| pubmed:dateCreated |
2011-5-9
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| pubmed:abstractText |
A novel synthetic route to a series of cerium bromide solvates is reported. The combination of bulk cerium bromide and the ionic liquid (IL) 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide results in a precursor paste that enhances the solubility of the cerium(III)bromide moiety in a number of donor solvents. Crystallization from these solvents has resulted in the isolation and characterization of CeBr(3)(THF)(4) (2), CeBr(3)(2-Me-THF)(4) (3), and CeBr(3)(MeCN)(5)·MeCN (4). Additionally, 2 is shown to be an efficient precursor for the new species CeBr(3)(py)(4) (5) and CeBr(3)(bipy)(py)(3) (6).
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
May
|
| pubmed:issn |
1520-510X
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
16
|
| pubmed:volume |
50
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
4627-31
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| pubmed:year |
2011
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| pubmed:articleTitle |
An ionic liquid-mediated route to cerium(III) bromide solvates.
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| pubmed:affiliation |
Chemistry Division, MS J582, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
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| pubmed:publicationType |
Journal Article
|