Linked Life Data

21438508

Source:http://linkedlifedata.com/resource/pubmed/id/21438508

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
2011-4-14
pubmed:abstractText
The multiple-mode two-dimensional infrared (2D-IR) spectrum in a broad frequency range from 1000 to 3200 cm(-1) of a 1-cyanovinyl acetate solution in CCl(4) is reported. By analyzing its relative orientations of the transition dipole moments of normal modes that cover vibrations of all chemical bonds, the three-dimensional molecular conformations and their population distributions of 1-cyanovinyl acetate are obtained, with the aid of quantum chemistry calculations that translate the experimental transition dipole moment cross angles into the cross angles among chemical bonds.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1520-5215
pubmed:author
pubmed:issnType
Electronic
pubmed:day
21
pubmed:volume
115
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3357-65
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Mapping molecular conformations with multiple-mode two-dimensional infrared spectroscopy.
pubmed:affiliation
Department of Chemistry, Rice University, Houston, Texas 77005, United States.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't