Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
10
pubmed:dateCreated
2011-7-1
pubmed:abstractText
Complex spectra of the KRb 420 nm system are analyzed by mass-resolved resonance enhanced two-photon ionization in a cold molecular beam. Vibronic structures of three singlet-singlet (4(1)?, 7(1)?(+), and 5(1)??X(1)?(+)) transitions were identified for the first time. By comparing with highly accurate ab initio calculations, we assigned the singlet excited electronic states, and determined their electronic term values and vibrational constants. Weak singlet-triplet transitions were observed and identified as the 5(3)?(0(+))?X(1)?(+) transitions by the homogeneous perturbation selection rule.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
1439-7641
pubmed:author
pubmed:copyrightInfo
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
pubmed:issnType
Electronic
pubmed:day
11
pubmed:volume
12
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2018-23
pubmed:year
2011
pubmed:articleTitle
Unravelling complex spectra of a simple molecule: REMPI study of the 420 nm band system of KRb.
pubmed:affiliation
Department of Chemistry, Mokpo National University, Muan-gun, Jeonnam 534-729, Korea.
pubmed:publicationType
Journal Article