Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
21
pubmed:dateCreated
2010-10-29
pubmed:abstractText
Indoles, when treated with dimethyl diazomalonate under catalysis by Cu(acac)(2), undergo C-H insertion reactions regioselectively depending on the substitution pattern on the indole moiety. Indoles where the 3-position is substituted give high yields of the C2-H insertion product. Microwave conditions are also disclosed which show comparable yields with reduced reaction times.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1523-7052
pubmed:author
pubmed:issnType
Electronic
pubmed:day
5
pubmed:volume
12
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4956-9
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Direct functionalization of indoles: copper-catalyzed malonyl carbenoid insertions.
pubmed:affiliation
Department of Chemistry, The University of Western Ontario, London, Ontario, Canada N6A 5B7.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't