Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
37
pubmed:dateCreated
2010-9-15
pubmed:abstractText
In this paper we focus upon the role of interfacial energetics in influencing the separation of charge transfer states into dissociated charge carriers in organic donor/acceptor blend films. In particular, we undertake transient optical studies of films comprising regioregular poly(3-hexylthiophene) (P3HT) blended with a series of perylene-3,4:9,10-tetracarboxydiimide (PDI) electron acceptors. For this film series, we observe a close correlation between the PDI electron affinity and the efficiency of charge separation. This correlation is discussed in the context of studies of charge photogeneration for other organic donor/acceptor blend films, including other polymers, blend compositions, and the widely used electron acceptor 3'-phenyl-3'H-cyclopropa[1,9](C(60)-I(h))[5,6]fullerene-3'-butanoic acid methyl ester (PCBM).
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
22
pubmed:volume
132
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
12919-26
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Acceptor energy level control of charge photogeneration in organic donor/acceptor blends.
pubmed:affiliation
Centre for Plastic Electronics, Department of Chemistry, Imperial College London, London, SW7 2AZ United Kingdom.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't