Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
17
pubmed:dateCreated
2010-8-30
pubmed:abstractText
The sediment to water diffusive flux of PAHs and PCBs was measured under field conditions with a novel infinite-sink benthic flux chamber that deployed semipermeable membrane devices (SPMD) as a sorbing material. Fluxes were measured before and after in situ capping of sediments in Oslo Harbour with clean clay. The fluxes of native pyrene and PCB 52 from uncapped contaminated sediment measured with the flux chamber were 0.3-1.6 microg m(-2) d(-1) and 2-8 ng m(-2) d(-1), respectively. Fluxes from the capped sediment were reduced by 93-97%. The in situ measured fluxes were compared to fluxes independently calculated from freely dissolved concentrations in pore water and overlying water, measured using equilibrium passive samplers, diffusive boundary layer (DBL) thickness, measured by an alabaster dissolution method and literature values of diffusion coefficients. Measured fluxes from the uncapped sediment agreed well with calculated fluxes, the median of the ratio of the measured flux over the calculated flux was 0.9 with an inter quartile range of 0.5-1.6.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1520-5851
pubmed:author
pubmed:issnType
Electronic
pubmed:day
1
pubmed:volume
44
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6752-9
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Field measurement of diffusional mass transfer of HOCs at the sediment-water interface.
pubmed:affiliation
Norwegian Geotechnical Institute, P.O. Box 3930, Ullevaal Stadion, NO-0806 Oslo, Norway. ee@ngi.no
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't