Linked Life Data

20695641

Source:http://linkedlifedata.com/resource/pubmed/id/20695641

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
34
pubmed:dateCreated
2010-8-25
pubmed:abstractText
Photochemical reactions of C(60) with siliranes (1a-d) afford adducts of four types (2a-5b) as carbosilylated and hydrosilylated C(60) derivatives. Characterization of these adducts was conducted using MS, UV, NMR spectroscopy, and single-crystal X-ray analyses. In particular, the first example of the crystal structure of a closed 1,2-adduct at the 5,6-ring junction of the C(60) cage is provided by single-crystal X-ray analysis of 3b. Electrochemical analyses also revealed unique redox properties of the products 2b-5b, which depend on the regiochemistry of the functionality, in addition to the substituents on the C(60) cage. Theoretical calculations offer bases for the experimentally observed redox properties and relative stabilities of the silylated products.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
1
pubmed:volume
132
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
12106-20
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Photochemical addition of C60 with siliranes: synthesis and characterization of carbosilylated and hydrosilylated C60 derivatives.
pubmed:affiliation
Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba 305-8577, Japan.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't