Linked Life Data

20540493

Source:http://linkedlifedata.com/resource/pubmed/id/20540493

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
26
pubmed:dateCreated
2010-6-30
pubmed:abstractText
The incorporation of carbon dioxide or argon stabilizes the structure of the microporous silica polymorph silicalite well beyond the stability range of tetrahedrally coordinated SiO(2) and, in fact, beyond even the metastability range of low-pressure silica polymorphs such as quartz and cristobalite at room temperature. The bulk modulus of silicalite strongly increases as a result of the incorporation of CO(2) or Ar and is equivalent to that of quartz. The insertion of these species deactivates the normal compression and pressure-induced amorphization mechanisms in this material, impeding the softening of low-energy vibrations, amorphization, and the eventual increase in silicon coordination up to at least 25 GPa.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
7
pubmed:volume
132
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8860-1
pubmed:year
2010
pubmed:articleTitle
Deactivation of pressure-induced amorphization in silicalite SiO2 by insertion of guest species.
pubmed:affiliation
Institut Charles Gerhardt Montpellier, UMR 5253 CNRS, Equipe C2M, Université Montpellier 2, Place E. Bataillon, cc1504, 34095 Montpellier cedex 5, France. jhaines@lpmc.univ-montp2.fr
pubmed:publicationType
Journal Article