Source:http://linkedlifedata.com/resource/pubmed/id/20419251
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
5
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pubmed:dateCreated |
2010-4-26
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pubmed:abstractText |
Gold nanoparticles dispersed in an ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (Au-BMI.PF(6)) and a binuclear nickel(II) complex ([Ni(2)(HBPPAMFF)mu-(OAc)(2)(H(2)O)]BPh(4)) immobilized on functionalized silica were successfully applied in the construction of a novel sensor for the determination of fisetin by square-wave voltammetry. Under optimized conditions, the analytical curve showed two linear ranges for fisetin concentrations from 0.28 to 1.39 microM and 2.77 to 19.50 microM with a detection limit of 0.05 microM. This sensor demonstrated suitable stability (ca. 150 days; at least 500 determinations) and good repeatability and reproducibility, with relative standard deviations of 2.91 and 5.11%, respectively. The recovery study of fisetin in apple juice samples gave values from 96.4 to 106.4%. The efficient analytical performance of the proposed sensor can be attributed to the effective immobilization of the Ni(ii)Ni(ii) complex on silica and the Au-BMI.PF(6) contribution to the electrode response.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/1-butyl-3-methylimidazolium...,
http://linkedlifedata.com/resource/pubmed/chemical/Flavonoids,
http://linkedlifedata.com/resource/pubmed/chemical/Gold,
http://linkedlifedata.com/resource/pubmed/chemical/Imidazoles,
http://linkedlifedata.com/resource/pubmed/chemical/Ionic Liquids,
http://linkedlifedata.com/resource/pubmed/chemical/Nickel,
http://linkedlifedata.com/resource/pubmed/chemical/Silicon Dioxide,
http://linkedlifedata.com/resource/pubmed/chemical/fisetin
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pubmed:status |
MEDLINE
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pubmed:month |
May
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pubmed:issn |
1364-5528
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:volume |
135
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1015-22
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pubmed:meshHeading |
pubmed-meshheading:20419251-Catalysis,
pubmed-meshheading:20419251-Electrochemical Techniques,
pubmed-meshheading:20419251-Electrodes,
pubmed-meshheading:20419251-Flavonoids,
pubmed-meshheading:20419251-Gold,
pubmed-meshheading:20419251-Imidazoles,
pubmed-meshheading:20419251-Ionic Liquids,
pubmed-meshheading:20419251-Metal Nanoparticles,
pubmed-meshheading:20419251-Nickel,
pubmed-meshheading:20419251-Silicon Dioxide
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pubmed:year |
2010
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pubmed:articleTitle |
Sensor for fisetin based on gold nanoparticles in ionic liquid and binuclear nickel complex immobilized in silica.
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pubmed:affiliation |
Laboratory of Biosensors, Department of Chemistry, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil. danielabrondani@hotmail.com
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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