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pubmed-article:20305725pubmed:issue9lld:pubmed
pubmed-article:20305725pubmed:dateCreated2010-4-1lld:pubmed
pubmed-article:20305725pubmed:abstractTextAu nanocages synthesized from Ag nanocubes via the galvanic replacement reaction are finding widespread use in a range of applications because of their tunable optical properties. Most of these applications require the use of nanocages with a uniform size and in large quantities. This requirement translates into a demand for scaling up the production of Ag nanocubes with uniform, well-controlled sizes. Here we report such a method based on the modification of NaHS-mediated polyol synthesis with argon protection for fast reduction, which allows for the production of Ag nanocubes on a scale of 0.1 g per batch. The Ag nanocubes had an edge length tunable from 25 to 45 nm together with a size variation within +/-5 nm. The use of argon protection was the key to the success of this scale-up synthesis, suggesting the importance of controlling oxidative etching during synthesis.lld:pubmed
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pubmed-article:20305725pubmed:authorpubmed-author:XiaYounanYlld:pubmed
pubmed-article:20305725pubmed:authorpubmed-author:ZhangQiangQlld:pubmed
pubmed-article:20305725pubmed:authorpubmed-author:ChenJingyiJlld:pubmed
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pubmed-article:20305725pubmed:pagination2044-8lld:pubmed
pubmed-article:20305725pubmed:dateRevised2011-9-26lld:pubmed
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pubmed-article:20305725pubmed:year2009lld:pubmed
pubmed-article:20305725pubmed:articleTitleProduction of Ag nanocubes on a scale of 0.1 g per batch by protecting the NaHS-mediated polyol synthesis with argon.lld:pubmed
pubmed-article:20305725pubmed:affiliationDepartments of Biomedical Engineering and of Chemistry, Washington University, St. Louis, Missouri 63130, USA.lld:pubmed
pubmed-article:20305725pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:20305725pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed
pubmed-article:20305725pubmed:publicationTypeResearch Support, N.I.H., Extramurallld:pubmed