Source:http://linkedlifedata.com/resource/pubmed/id/20200736
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
11
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pubmed:dateCreated |
2010-3-4
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pubmed:abstractText |
The interaction between sulfur-containing chromophores and cationic species (K(+)) has been investigated in dye-loaded zeolite materials by means of photoluminescence spectroscopy. A red-shift in the emission spectra of the host-guest compounds (HGCs) has been detected and unambiguously connected to the close proximity between a conjugated moiety and nearby free charges, suggesting a specific role played by sulfur lone pair electrons. Quantum-chemical calculations on model compounds have been performed to support this hypothesis.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Mar
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pubmed:issn |
1463-9084
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
20
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pubmed:volume |
12
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2599-605
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pubmed:meshHeading | |
pubmed:year |
2010
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pubmed:articleTitle |
Weak forces at work in dye-loaded zeolite materials: spectroscopic investigation on cation-sulfur interactions.
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pubmed:affiliation |
Università degli Studi di Milano Bicocca and INFM, Dipartimento di Scienza dei Materiali, via R.Cozzi 53, I-20125 Milano, Italy. giorgio.macchi@mater.unimib.it
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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