Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2010-1-20
pubmed:abstractText
Using reversible polymerization and depolymerization reactions in a single crystal state, we achieved a reversible transformation from a nanocluster to a coordination polymer. During the interconversion, the structural frameworks switched between nonporous hexanuclear clusters and porous double-zigzag chains; the magnetic behaviors switched between paramagnetism and metamagnetism, respectively. The microporous framework, which had 1D channels 1.9 A x 3.6 A in size, exhibited selective gas adsorption of H(2) and CO(2) over N(2).
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
27
pubmed:volume
132
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
912-3
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Interconversion between a nonporous nanocluster and a microporous coordination polymer showing selective gas adsorption.
pubmed:affiliation
Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Ksuga-koen, Fukuoka, 816-8580, Japan.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't