Source:http://linkedlifedata.com/resource/pubmed/id/20039630
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
3
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pubmed:dateCreated |
2010-1-20
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pubmed:abstractText |
Using reversible polymerization and depolymerization reactions in a single crystal state, we achieved a reversible transformation from a nanocluster to a coordination polymer. During the interconversion, the structural frameworks switched between nonporous hexanuclear clusters and porous double-zigzag chains; the magnetic behaviors switched between paramagnetism and metamagnetism, respectively. The microporous framework, which had 1D channels 1.9 A x 3.6 A in size, exhibited selective gas adsorption of H(2) and CO(2) over N(2).
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1520-5126
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
27
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pubmed:volume |
132
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
912-3
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pubmed:meshHeading |
pubmed-meshheading:20039630-Adsorption,
pubmed-meshheading:20039630-Crystallography, X-Ray,
pubmed-meshheading:20039630-Gases,
pubmed-meshheading:20039630-Models, Molecular,
pubmed-meshheading:20039630-Nanoparticles,
pubmed-meshheading:20039630-Organometallic Compounds,
pubmed-meshheading:20039630-Polymers,
pubmed-meshheading:20039630-Porosity,
pubmed-meshheading:20039630-Surface Properties
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pubmed:year |
2010
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pubmed:articleTitle |
Interconversion between a nonporous nanocluster and a microporous coordination polymer showing selective gas adsorption.
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pubmed:affiliation |
Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Ksuga-koen, Fukuoka, 816-8580, Japan.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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