Source:http://linkedlifedata.com/resource/pubmed/id/19891828
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
|
| pubmed:dateCreated |
2009-11-6
|
| pubmed:abstractText |
A time-resolved soft-pulse dynamic compression attenuated total reflection (ATR) step-scan Fourier transform rheo-optical system has been developed. This system was used to observe different viscoelastic properties of polyethyleneterephthalate (PET) and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHx). Resonance features were observed in the dynamic compression ATR spectrum of PHBHx with 625 Hz soft-pulse frequency. In contrast, the dynamic compression ATR spectrum of PET showed no resonance features. The resonance feature of PHBHx was found at 1723 cm(-1), which corresponds to the structural or morphological reorganization of a less ordered (Type II) crystalline form under compressive perturbation. The time-resolved evolution of infrared (IR) spectra was effectively analyzed by conventional generalized two-dimensional (2D) correlation analysis. The 2D-IR results indicate that the dynamic response of the well-ordered Type I crystalline state (1289 and 1261 cm(-1)) is faster than that of the Type II (1723, 1277, and 1228 cm(-1)). The present method shows promise for characterizing a wide variety of viscoelastic materials, including polymer alloys, blends, composites, and copolymers, and semicrystalline polymers.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Nov
|
| pubmed:issn |
1943-3530
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
63
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
1204-10
|
| pubmed:year |
2009
|
| pubmed:articleTitle |
Rheo-optical study of polymers by using time-resolved soft-pulse compression attenuated total reflection step-scan Fourier transform infrared spectroscopy.
|
| pubmed:affiliation |
Material Analysis Division, Material Technology R&D Laboratories, Konica Minolta Technology Center Inc., 1 Sakura-machi, Hino-shi, Tokyo, 191-8511, Japan. yuji.nishikawa@konicaminolta.jp
|
| pubmed:publicationType |
Journal Article
|