19533703

Source:http://linkedlifedata.com/resource/pubmed/id/19533703

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0034760, umls-concept:C0449444, umls-concept:C0457555, umls-concept:C1956166
pubmed:issue	29
pubmed:dateCreated	2009-7-14
pubmed:abstractText	A simple but effective copper-catalyzed borylation of aryl halides, including electron-rich and sterically hindered aryl bromides, with alkoxy diboron reagents occurs under mild conditions (see scheme). Preliminary DFT studies of the mechanism suggest that sigma-bond metathesis between a copper-boryl intermediate and the aryl halide generates the aryl boronate product.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/0370543
pubmed:status	PubMed-not-MEDLINE
pubmed:issn	1521-3773
pubmed:author	pubmed-author:DangLiL, pubmed-author:KleebergChristianC, pubmed-author:LinZhenyangZ, pubmed-author:MarderTodd BTB
pubmed:issnType	Electronic
pubmed:volume	48
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	5350-4
pubmed:year	2009
pubmed:articleTitle	A facile route to aryl boronates: room-temperature, copper-catalyzed borylation of aryl halides with alkoxy diboron reagents.
pubmed:affiliation	Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK.
pubmed:publicationType	Journal Article