19373817

Source:http://linkedlifedata.com/resource/pubmed/id/19373817

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0007382, umls-concept:C0302583, umls-concept:C1413247, umls-concept:C2636920, umls-concept:C2828360
pubmed:issue	21
pubmed:dateCreated	2009-5-11
pubmed:abstractText	Hooking up: FeCl(2) catalyzes the efficient cross dehydrogenative arylation of substrates having benzylic C-H bonds (see scheme). High regioselectivity was observed during the cross-coupling between compounds containing aromatic C(sp(2))-H bonds and benzylic C(sp(3))-H bonds. This process is proposed to proceed by single-electron-transfer oxidation and Friedel-Crafts alkylation.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/0370543
pubmed:status	PubMed-not-MEDLINE
pubmed:issn	1521-3773
pubmed:author	pubmed-author:LiBi-JieBJ, pubmed-author:LiYi-ZhouYZ, pubmed-author:LinSongS, pubmed-author:LuXing-YuXY, pubmed-author:ShiZhang-JieZJ
pubmed:issnType	Electronic
pubmed:volume	48
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3817-20
pubmed:year	2009
pubmed:articleTitle	Cross dehydrogenative arylation (CDA) of a benzylic C-H bond with arenes by iron catalysis.
pubmed:affiliation	PKU Green Chemistry Centre and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
pubmed:publicationType	Journal Article