Reinvestigation of a Ru(2)-incorporated polyoxometalate dioxygenase precatalyst, "[WZnRu(2)(III)(H(2)O)(OH)(ZnW(9)O(34))(2)](11-)": evidence for marginal, <or=0.2 equivalents of Ru incorporation plus faster catalysis by physical mixtures of [Ru(II)(DMSO)(4)Cl(2)] and the parent polyoxometalate [WZn(3)(H(2)O)(2)(ZnW(9)O(34))(2)](12-).
Source:http://linkedlifedata.com/resource/pubmed/id/19351133
Inorg Chem
2009
May
18
48
10
4411-20
