Source:http://linkedlifedata.com/resource/pubmed/id/19254002
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
7
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pubmed:dateCreated |
2009-3-26
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pubmed:abstractText |
Chiral allenamides are prepared with high levels of enantiomeric purity by [2,3]-sigmatropic rearrangement of propargylic sulfimides. The required branched propargylic sulfides are prepared by an enantioselective organocatalytic aldehyde alpha-sulfenylation followed by Corey-Fuchs alkynylation.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Aldehydes,
http://linkedlifedata.com/resource/pubmed/chemical/Alkadienes,
http://linkedlifedata.com/resource/pubmed/chemical/Amides,
http://linkedlifedata.com/resource/pubmed/chemical/Sulfides,
http://linkedlifedata.com/resource/pubmed/chemical/propadiene
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pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1523-7052
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
2
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pubmed:volume |
11
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1547-50
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pubmed:meshHeading | |
pubmed:year |
2009
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pubmed:articleTitle |
Enantioselective synthesis of allenamides via sulfimide [2,3]-sigmatropic rearrangement.
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pubmed:affiliation |
Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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