19235191

Source:http://linkedlifedata.com/resource/pubmed/id/19235191

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0001052, umls-concept:C0005304, umls-concept:C0015075, umls-concept:C0443286, umls-concept:C0459800, umls-concept:C0598128
pubmed:issue	15
pubmed:dateCreated	2009-3-30
pubmed:abstractText	Getting the bends: The dynamics of 1,3-dipolar cycloaddition reactions have been explored by decomposing transition vector, quasi-classical trajectories, and single trajectories. Dipole bending (see picture) makes the largest contribution to the TS distortion energy and constitutes the major part of transition-state distortion energy in the favored concerted pathway.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/0370543
pubmed:status	PubMed-not-MEDLINE
pubmed:issn	1521-3773
pubmed:author	pubmed-author:DoubledayCharles ECE, pubmed-author:HoukK NKN, pubmed-author:SrcicStaneS
pubmed:issnType	Electronic
pubmed:volume	48
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2746-8
pubmed:year	2009
pubmed:articleTitle	Dynamics of 1,3-dipolar cycloaddition reactions of diazonium betaines to acetylene and ethylene: bending vibrations facilitate reaction.
pubmed:affiliation	Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095-1569, USA.
pubmed:publicationType	Journal Article