pubmed-article:19209592 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:19209592 | lifeskim:mentions | umls-concept:C0035820 | lld:lifeskim |
pubmed-article:19209592 | lifeskim:mentions | umls-concept:C0031180 | lld:lifeskim |
pubmed-article:19209592 | lifeskim:mentions | umls-concept:C0311404 | lld:lifeskim |
pubmed-article:19209592 | lifeskim:mentions | umls-concept:C1522240 | lld:lifeskim |
pubmed-article:19209592 | lifeskim:mentions | umls-concept:C1521827 | lld:lifeskim |
pubmed-article:19209592 | lifeskim:mentions | umls-concept:C0599956 | lld:lifeskim |
pubmed-article:19209592 | pubmed:issue | 1 | lld:pubmed |
pubmed-article:19209592 | pubmed:dateCreated | 2009-2-12 | lld:pubmed |
pubmed-article:19209592 | pubmed:abstractText | The oxidative reactivity of THF derivatives formed during THF/nC60 synthesis was evaluated with indigo dye as a model compound. The results showed that the formation of previously undetected oxidizing agents during THF/nC60 synthesis accounted for the degradation of indigo dye by THF/nC60 (THF/nC60/unwashed), while THF/nC60 after vigorous washing (THF/nC60/washed) and nC60 prepared without the use of THF were not reactive. gamma-Butyrolactone (GBL) was detected by GC-MS in the THF/nC60/unwashed as one of THF derivatives, but showed no reactivity with indigo dye. An organic peroxide was detected in the THF/nC60/unwashed by HPLC, and was reactive with indigo dye. This compound was found to also account for the elevated antibacterial and bactericidal activities of THF/nC60/unwashed on E. coli. Analysis by LC/(+ESI)MS and 1H NMR showed that the detected THF peroxide was tetrahydro-2-(tetrahydrofuran-2-ylperoxy)furan. The formation of THF peroxide during the preparation of aqueous stable C60 aggregates provides another potential explanation for the reactivity and oxidative stress mechanisms of THF/nC60 system reported in the literature, although it does not exclude the potential reactivity and toxicity of nC60 itself. | lld:pubmed |
pubmed-article:19209592 | pubmed:language | eng | lld:pubmed |
pubmed-article:19209592 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19209592 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:19209592 | pubmed:month | Jan | lld:pubmed |
pubmed-article:19209592 | pubmed:issn | 0013-936X | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:KayD WDW | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:KimJae-HongJH | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:ZhangBoB | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:HughesJoseph... | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:LeeJaesangJ | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:HuangChing-Hu... | lld:pubmed |
pubmed-article:19209592 | pubmed:author | pubmed-author:FortnerJohn... | lld:pubmed |
pubmed-article:19209592 | pubmed:issnType | Print | lld:pubmed |
pubmed-article:19209592 | pubmed:day | 1 | lld:pubmed |
pubmed-article:19209592 | pubmed:volume | 43 | lld:pubmed |
pubmed-article:19209592 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:19209592 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:19209592 | pubmed:pagination | 108-13 | lld:pubmed |
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pubmed-article:19209592 | pubmed:year | 2009 | lld:pubmed |
pubmed-article:19209592 | pubmed:articleTitle | Delineating oxidative processes of aqueous C60 preparations: role of THF peroxide. | lld:pubmed |
pubmed-article:19209592 | pubmed:affiliation | School of Civil and Environmental Engineering, Georgia Institute of Technology, 200 Bobby Dodd Way, Atlanta, Georgia 30332, USA. | lld:pubmed |
pubmed-article:19209592 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:19209592 | pubmed:publicationType | Research Support, U.S. Gov't, Non-P.H.S. | lld:pubmed |
pubmed-article:19209592 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:19209592 | lld:pubmed |