Linked Life Data

19050781

Source:http://linkedlifedata.com/resource/pubmed/id/19050781

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
48
pubmed:dateCreated
2008-12-3
pubmed:abstractText
A new Fe(III)(6) cluster, [Fe(3)L(2)(ida)(mu-OH)(3)(mu-O)](2).4ClO(4).2CH(3)OH.8H(2)O (1) (where L = N-methyl-N,N-bis(2-pyridylmethyl)amine; H(2)ida = iminodiacetic acid), has been synthesized and magnetic properties are shown. The asymmetric unit of 1 contains a triangular [Fe(3)L(2)(ida)(mu-OH)(3)(mu-O)](2+) unit and two such trinuclear units are further connected by two ida(2-), generating a hexanuclear Fe(III) core in 1. Variable temperature magnetic susceptibility studies reveal the presence of dominant antiferromagnetic exchange interactions and the variable-field and temperature magnetization measurements establish that each Fe(3) cluster has S = 5/2 ground state and the coupling between the two moieties is almost zero.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Dec
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
28
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6948-52
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
A new Fe(6) ferric cluster: synthesis, crystal structure and magnetic properties.
pubmed:affiliation
Department of Chemistry, Nankai University, Tianjin, China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't