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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
34
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pubmed:dateCreated |
2008-11-21
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pubmed:abstractText |
Transfer hydrogenation from 2-propanol to CO/4-methylstyrene and CO/styrene polyketones was catalyzed by [Ir(diene)(N-N)X] (N-N = nitrogen chelating ligand; X = halogen) in the presence of a basic cocatalyst. The reactions were performed using dioxane as cosolvent, in order to overcome problems due to low polyketone solubility. The polyalcohols were obtained in yields up to 95%, the conversions being markedly dependent on the nature of the ligands coordinated to iridium as well as on the experimental conditions.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
1477-9226
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:day |
14
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4659-63
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pubmed:meshHeading |
pubmed-meshheading:19024366-Acetophenones,
pubmed-meshheading:19024366-Biocompatible Materials,
pubmed-meshheading:19024366-Borohydrides,
pubmed-meshheading:19024366-Catalysis,
pubmed-meshheading:19024366-Hydrogen,
pubmed-meshheading:19024366-Iridium,
pubmed-meshheading:19024366-Ketones,
pubmed-meshheading:19024366-Lithium Compounds,
pubmed-meshheading:19024366-Magnetic Resonance Spectroscopy,
pubmed-meshheading:19024366-Organometallic Compounds,
pubmed-meshheading:19024366-Oxidation-Reduction,
pubmed-meshheading:19024366-Styrenes
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pubmed:year |
2008
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pubmed:articleTitle |
Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials.
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pubmed:affiliation |
Dipartimento di Scienze Chimiche, Università di Trieste, Via Giorgieri 1, 34127, Trieste, Italy.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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