Source:http://linkedlifedata.com/resource/pubmed/id/18975873
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
47
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| pubmed:dateCreated |
2009-2-20
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| pubmed:abstractText |
A hydrogen-mediated Ru-C to Ru-B bond conversion was observed experimentally and supported by the theoretical calculations. Treatment of [eta(5):sigma(C)-Me(2)C(C(5)H(4))(C(2)B(10)H(10))]Ru(COD) (1) bearing a Ru-C(cage) sigma bond with PR(3) in the presence of H(2) gave Ru-B(cage) bonded complexes [eta(5):sigma(B)-Me(2)C(C(5)H(4))(C(2)B(10)H(10))]RuH(2)(PR(3)) (R = Cy (2), Ph (3)) (sigma(C): Ru-C(cage) sigma bond; sigma(B): Ru-B(cage) sigma bond). Complex 3 was converted to [eta(5):sigma(B)-Me(2)C(C(5)H(4))(C(2)B(10)H(10))]Ru(L(2)) in the presence of L(2) (L(2) = dppe (4), PPh(3)/P(OEt)(3) (5), PPh(3)/pyridine (6)) via liberation of H(2) upon heating. These complexes were fully characterized by various spectroscopic techniques, elemental analyses, and single-crystal X-ray diffraction studies. DFT calculations show that this conversion process is both kinetically and thermodynamically favorable and requires involvement of a hydride ligand.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Nov
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| pubmed:issn |
1520-5126
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
26
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| pubmed:volume |
130
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
16103-10
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| pubmed:year |
2008
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| pubmed:articleTitle |
Hydrogen-mediated metal-carbon to metal-boron bond conversion in metal-carboranyl complexes.
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| pubmed:affiliation |
Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China.
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| pubmed:publicationType |
Journal Article
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