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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
1
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pubmed:dateCreated |
2009-1-13
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pubmed:abstractText |
Dynamic nuclear polarization is combined with temperature-jump methods to develop a new 2D 13C-13C NMR experiment that yields a factor of 100-170 increase in sensitivity. The polaization step is performed at 100 K, and the sample is subsequently melted with a 10.6 microm laser pulse to yield a sample with highly polarized 13C spins. 13C detected 2D 13C-13C spectroscopy is performed in the usual manner.
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pubmed:grant |
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pubmed:commentsCorrections |
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-11916398,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-12137529,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-12766412,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-14599177,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-15339160,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-15928994,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-16848479,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-16910679,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-16939261,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-17286492,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-17719814,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-17942352,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-18266438,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18942782-9139651
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1520-5126
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pubmed:author |
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pubmed:issnType |
Electronic
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pubmed:day |
14
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pubmed:volume |
131
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
12-3
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pubmed:dateRevised |
2011-9-26
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pubmed:meshHeading |
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pubmed:year |
2009
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pubmed:articleTitle |
In situ temperature-jump dynamic nuclear polarization: enhanced sensitivity in two dimensional 13C-13C correlation spectroscopy in solution.
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pubmed:affiliation |
Francis Bitter Magnet Laboratory and Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
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pubmed:publicationType |
Journal Article,
Research Support, N.I.H., Extramural
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