Source:http://linkedlifedata.com/resource/pubmed/id/18764178
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
2
|
| pubmed:dateCreated |
2008-9-3
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| pubmed:abstractText |
The molecular-frame photoelectron angular distribution (MFPAD) of the satellite accompanying the C 1s photoline of the CO2 molecule has been measured at the C 1s(2sigmag)-->4sigmau* shape resonance, using electron-ion multicoincidence momentum spectroscopy. The observed MFPAD indicates that the conjugate satellite is excited by internal inelastic scattering. In this scenario, a photoelectron is ejected from the C 1s(2sigmag) orbital along the molecular axis and collides with an O lone-pair electron in the highest occupied molecular orbital 1pig. Then one of the colliding electrons is trapped to the lowest unoccupied molecular orbital 2piu*, while the other is emitted as a satellite photoelectron of sigmag symmetry, losing the information of the original photoelectron emission direction and parity.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
0031-9007
|
| pubmed:author |
pubmed-author:CassimiAA,
pubmed-author:CzaschAA,
pubmed-author:DörnerRR,
pubmed-author:De FanisAA,
pubmed-author:FukuzawaHH,
pubmed-author:KoyanoII,
pubmed-author:RohS SSS,
pubmed-author:SaitoNN,
pubmed-author:SchmidtLL,
pubmed-author:TakahashiMM,
pubmed-author:TeranishiTT,
pubmed-author:UedaKK,
pubmed-author:YoshidaHH
|
| pubmed:issnType |
Print
|
| pubmed:day |
11
|
| pubmed:volume |
101
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
023001
|
| pubmed:year |
2008
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| pubmed:articleTitle |
Internal inelastic scattering satellite probed by molecular-frame photoelectron angular distributions from CO2.
|
| pubmed:affiliation |
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan.
|
| pubmed:publicationType |
Journal Article
|