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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
16
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pubmed:dateCreated |
2008-8-8
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pubmed:abstractText |
We have succeeded in the first versatile iodoarene-catalyzed C-C bond-forming reactions by development of a new reoxidation system at low temperatures using stoichiometric bis(trifluoroacetyl) peroxide A in 2,2,2-trifluoroethanol (TFE). The catalytic system supplies a wide range of substrates and functional availabilities sufficient to be used in the key synthetic process of producing biologically important Amaryllidaceae alkaloids.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
1523-7052
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pubmed:author |
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pubmed:issnType |
Electronic
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pubmed:day |
21
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pubmed:volume |
10
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
3559-62
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pubmed:meshHeading |
pubmed-meshheading:18616338-Catalysis,
pubmed-meshheading:18616338-Hydrocarbons, Iodinated,
pubmed-meshheading:18616338-Hydrogen Peroxide,
pubmed-meshheading:18616338-Ketones,
pubmed-meshheading:18616338-Molecular Structure,
pubmed-meshheading:18616338-Oxidation-Reduction,
pubmed-meshheading:18616338-Peroxides,
pubmed-meshheading:18616338-Phenols,
pubmed-meshheading:18616338-Spiro Compounds,
pubmed-meshheading:18616338-Temperature,
pubmed-meshheading:18616338-Trifluoroacetic Acid,
pubmed-meshheading:18616338-Trifluoroethanol
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pubmed:year |
2008
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pubmed:articleTitle |
A new H2O2/acid anhydride system for the iodoarene-catalyzed C-C bond-forming reactions of phenols.
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pubmed:affiliation |
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka, 565-0871 Japan.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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