Source:http://linkedlifedata.com/resource/pubmed/id/18613676
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
31
|
| pubmed:dateCreated |
2008-7-30
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| pubmed:abstractText |
Reversible mechanochromic luminescence of [(C6F5Au)2(mu-1,4-diisocyanobenzene)] is reported. Grinding of the complex induced a photoluminescent color change, which was restored by exposure to a solvent. This cycle was repeated 20 times with no color degradation in the emissions. Their optical properties, X-ray crystallographic analysis, IR, and XRD measurements strongly suggested that the change in the molecular arrangement is responsible for this mechanochromic property. Intermolecular aurophilic bondings presumably play a key role in the altered emission.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Aug
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| pubmed:issn |
1520-5126
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| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
6
|
| pubmed:volume |
130
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
10044-5
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| pubmed:dateRevised |
2009-1-6
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| pubmed:year |
2008
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| pubmed:articleTitle |
Reversible mechanochromic luminescence of [(C6F5Au)2(mu-1,4-diisocyanobenzene)].
|
| pubmed:affiliation |
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. hajito@sci.hokudai.ac.jp
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| pubmed:publicationType |
Journal Article
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