Linked Life Data

18563897

Source:http://linkedlifedata.com/resource/pubmed/id/18563897

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
28
pubmed:dateCreated
2008-7-9
pubmed:abstractText
Electrospray ionization tandem mass spectrometry of a phosphonium ylid complex of gold produces an ion whose mass and gas-phase chemical reactivity indicate that it is a gold benzylidene complex. The complex, with a supporting NHC ligand, corresponds to a type of reactive intermediates which have been presumed to act in gold-catalyzed cyclopropanation reactions, but which have not been observed to date in solution or gas-phase experiments. A threshold CID experiment also yields thermochemical information on the formation of the gold carbene from the ylid complex precursor.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
16
pubmed:volume
130
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8880-1
pubmed:year
2008
pubmed:articleTitle
Gas-phase synthesis and reactivity of a gold carbene complex.
pubmed:affiliation
Laboratorium für Organische Chemie, ETH Zürich, Wolfgang-Pauli-Strasse 10, CH-8093, Switzerland.
pubmed:publicationType
Journal Article