Source:http://linkedlifedata.com/resource/pubmed/id/18537426
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
21
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| pubmed:dateCreated |
2008-6-9
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| pubmed:abstractText |
The rotationally resolved electronic spectra of the electronic origin of the 7-azaindole-(H(2)O)(1) and of the 7-azaindole-(H(2)O)(2) clusters have been measured in a molecular beam. From the rotational constants the structures in the S(0) and S(1) electronic states were determined as cyclic with the pyrrolo NH and the pyridino N atoms being bridged by one and two water molecules, respectively. Excited state lifetimes of about 10 ns for both clusters have been found. In the spectrum of the 7-azaindole-(H(2)O)(2) cluster a splitting of the rovibronic band is observed, which can be traced back to a large amplitude motion, involving the out-of-plane hydrogen atoms of the water chain. Both the changes of the rotational constants upon electronic excitation and the orientation of the transition dipole point to a solvent induced state reversal between the L(a) and the L(b) states upon microsolvation.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jun
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| pubmed:issn |
1089-7690
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
7
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| pubmed:volume |
128
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
214311
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| pubmed:year |
2008
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| pubmed:articleTitle |
Rotationally resolved electronic spectroscopy of water clusters of 7-azaindole.
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| pubmed:affiliation |
Institut für Physikalische Chemie I, Heinrich-Heine-Universität, D-40225 Düsseldorf, Germany.
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| pubmed:publicationType |
Journal Article
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