Linked Life Data

18500803

Source:http://linkedlifedata.com/resource/pubmed/id/18500803

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
24
pubmed:dateCreated
2008-6-12
pubmed:abstractText
Diethyl ether added as an entrainer (cosolvent) to near- and supercritical CO2 significantly enhanced the enantioselectivity of photocyclization of 5,5-diphenyl-4-penten-1-ol sensitized by saccharide naphthalenedicarboxylate to give a cyclization product in enantiomeric excesses much larger than those obtained in conventional organic solvents, revealing the unique features of nc- and sc-CO2 as well as the critical role of entrainer clustering to the intervening diastereomeric exciplex pair.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
18
pubmed:volume
130
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7526-7
pubmed:dateRevised
2008-12-18
pubmed:year
2008
pubmed:articleTitle
Entrainer effect on photochirogenesis in near- and supercritical carbon dioxide: dramatic enhancement of enantioselectivity.
pubmed:affiliation
Department of Applied Chemistry, Osaka University, Suita 565-0871, Japan.
pubmed:publicationType
Journal Article