Linked Life Data

18461205

Source:http://linkedlifedata.com/resource/pubmed/id/18461205

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
18
pubmed:dateCreated
2008-5-7
pubmed:abstractText
A new fluorenyl-substituted dioxotetraamine salicylaldehyde Schiff-base ligand (L1) has been synthesized by the non-template 1 + 2 condensation of ligand 6-(9-fluorenyl)-1,4,8,11-tetraazaundecane-5,7-dione (L) with salicylaldehyde. From reduction of L1 with an excess of NaBH4, a ditopic dioxotetraamine ligand (L2) has been obtained. The copper(II) complex of L1 has been synthesized and its properties were examined by ES-MS and variable-temperature magnetic susceptibility as well as its crystal structure being determined. Detailed studies have been made on solution chemistry of Cu(II) complex of L2 by pH-potentiometric and fluorometric titration.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
14
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2487-94
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
New fluorenyl-substituted ditopic dioxotetraamine ligands and their copper(II) complexes--synthesis, crystal structure, magnetic properties and solution behavior.
pubmed:affiliation
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't