Linked Life Data

18414752

Source:http://linkedlifedata.com/resource/pubmed/id/18414752

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
17
pubmed:dateCreated
2008-4-16
pubmed:abstractText
A ligand field analysis of two structurally related hexanuclear Mn(iii) coordination complexes reveals that the observed difference in their ground spin-state anisotropy originates from the difference in projection coefficients of the single-ion anisotropy to spin states of different total spin quantum-number, S, rather than the geometrical distortions of the metal ions. Furthermore we show that the single-ion second order anisotropy induces fourth and higher order anisotropy terms to the ground spin states of the studied systems, as a consequence of spin-state mixing effects due to the comparable magnitude of the single-ion second order anisotropy and the isotropic exchange parameters.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
May
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
7
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2277-84
pubmed:year
2008
pubmed:articleTitle
A ligand-field study of the ground spin-state magnetic anisotropy in a family of hexanuclear Mn(III) single-molecule magnets.
pubmed:affiliation
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Denmark. piligkos@kiku.dk
pubmed:publicationType
Journal Article